12. Brad Pitt and Jennifer Aniston
The two met on a blind date set up by their agents. It went so well that they were married two years later in 2000. Pitt appeared on an Episode of Friends but their marriage broke apart by 2005.
It wasn’t a good split as there was the whole affair with Angelina Jolie after she and Brad Pitt appeared together in “Mr. and Mrs. Smith.”
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