Brad Pitt & Angelina Jolie Met on the set of “Mr. & Mrs. Smith”
When filming Mr. and Mrs. Smith , Pitt was married to Jennifer Aniston and Jolie had recently filed for divorce from Billy Bob Thornton. Jolie said, “… I think we found this strange friendship and partnership that kind of just suddenly happened. I think a few months in I realized, ‘God, I can’t wait to get to work.’”
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Jolie also said, “It took until, really, the end of the shoot for us, I think, to realize that it might mean something more than we’d earlier allowed ourselves to believe. And both knowing that the reality of that was a big thing, something that was going to take a lot of serious consideration.” In 2005, the couple started being seen together as a couple. In 2014, the couple secretly got married in France. Unfortunately, they’re no longer together today. The news of their divorce came out in 2016.